Glass was used since stone age for making sharp cutting tools. It was a natural product of volcanic eruptions. The earliest known glass objects, of the mid third millennium BCE, were beads, perhaps initially created as accidental by-products of metal-working.

According to Pliny the Elder, Phoenician traders were the first to stumble upon glass manufacturing techniques at the site of the Belus River. Georgius Agricola, in De re metallica, reported a traditional serendipitous “discovery” tale of familiar type :
“The tradition is that a merchant ship laden with nitrum being moored at this place, the merchants were preparing their meal on the beach, and not having stones to prop up their pots, they used lumps of nitrum from the ship, which fused and mixed with the sands of the shore, and there flowed streams of a new translucent liquid, and thus was the origin of glass.”

This account is more a reflection of Roman experience of glass production, however, as white silica sand from this area was used in the production of glass within the Roman Empire due to its high purity levels.

During the 1st century BCE glass blowing was discovered on the Syro-Judean coast, revolutionizing the industry. Glass vessels were now inexpensive compared to pottery vessels. A growth of the use of glass products occurred throughout the Roman world. Glass became the Roman plastic, and glass containers produced in Alexandria spread throughout the Roman Empire. With the discovery of clear glass (through the introduction of manganese dioxide), by glass blowers in Alexandria circa 100 CE, the Romans began to use glass for architectural purposes. Cast glass windows, albeit with poor optical qualities, began to appear in the most important buildings in Rome and the most luxurious villas of Herculaneum and Pompeli. Over the next 1,000 years glass making and working continued and spread through southern Europe and beyond.

INDIA

Indigenous development of glass technology in South Asia may have begun in 1730 BCE. Evidence of this culture includes a red-brown glass bead along with a hoard of beads dating to that period, making it the earliest attested glass from the Indus Valley locations. Glass discovered from later sites dating from 600􀁇300 BCE displays common color.

Chalcolithic evidence of glass has been found in Hastinapur, India. Some of the texts which mention glass in India are the Shatapatha Brahmana and Vinaya Pitaka. However, the first unmistakable evidence in large quantities, dating from the 3rd century BCE, has been uncovered from the archaeological site in Takshashila, ancient India.

By the 1st century CE, glass was being used for ornaments and casing in South Asia. Contact with the Greco-Roman world added newer techniques, and Indians artisans mastered several techniques of glass molding, decorating and coloring by the succeeding centuries. The Satavahana period of India also produced short cylinders of composite glass.